TRIS(5-ACETYL-3-THIENYL)METHANE CYCLONONANONE (1 1) INCLUSION COMPOUND/

Authors
Citation
L. Pang et F. Brisse, TRIS(5-ACETYL-3-THIENYL)METHANE CYCLONONANONE (1 1) INCLUSION COMPOUND/, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1947-1950
Citations number
11
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
12
Pages
1947 - 1950
Database
ISI
SICI code
0108-2701(1994)50:<1947:TC(1IC>2.0.ZU;2-S
Abstract
Tris(5-acetyl-3-thienyl)methane (TATM) forms an inclusion compound wit h cyclononanone in a host/guest ratio of 1/1, C19H16O3S3.C9H16O. The c rystal belongs to the monoclinic system. The cavity formed by the TATM molecule is of a zigzag-channel type, parallel to the c axis. The cyc lononanone guest molecule occupies two orientationally disordered posi tions with occupation factors of 25 and 75%. The two cyclononanone mol ecules each have the (g(-)g(-)ggg(-)g(-)sg(-)s) conformation.