(R,S)-1-PHENYLETHYLAMMONIUM (S)-MANDELATE

Authors
Citation
Hl. Dediego, (R,S)-1-PHENYLETHYLAMMONIUM (S)-MANDELATE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1995-1998
Citations number
8
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
12
Pages
1995 - 1998
Database
ISI
SICI code
0108-2701(1994)50:<1995:((>2.0.ZU;2-T
Abstract
The asymmetric unit of the title compound, C8H12N+. C8H7O3-, contains two 1-phenylethylammonium cations with opposite configurations and two (S)-mandelate anions (alpha-hydroxybenzeneacetate). The ions are show n to be nearly related by a pseudo inversion centre. This gives rise t o an unusual conformation of one of the (S)-mandelate ions. An extensi ve hydrogen-bond system connects the ions in a similar way to the hydr ogen-bond patterns found in (S)-1-phenylethylammonium (S)-mandelate an d (R)-mandelate.