Va. Mikhailov et al., MASS-SPECTROMETRIC AND OPTICAL STUDY OF PRODUCTS FROM LASER-ABLATED PBTE(GA), Russian chemical bulletin, 43(2), 1994, pp. 202-205
The products of evaporation (p = 10(-7) Torr) from the surface of a Pb
Te(Ga) target ablated by a focused Nd3+: YAl-laser(lambda = 1.08 mu m,
tau = 15 ns, w = 0.47 divided by 4.8 J cm(-2)) have been studied usin
g quadrupole mass spectrometry and optical spectrometry. Neutral Pb, T
e, Ga, Te-2, and PbTe and singly charged ions of Pb, Te, and Ga were d
etected by mass spectrometry. The lines of Pb-I, Pb-II, Te-II, and Ga-
I were observed in the 340 divided by 760 nm region in the emission sp
ectra; the lines of Pb-III and Te-III were absent. The time-current de
pendences of ions passed through a mass-filter for each vapor componen
t at different w and for the generation of the crater on the target su
rface were studied. The kinetic energy of the ions was estimated using
an ion-optical decelerating lens. The temperature of the laser plasma
was estimated from the intensities of the Pb-I lines.