PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .37. REDOX PROPERTIES AND ELECTROCHEMICAL POLYMERIZATION OF METHACRYLOYLACETONE ANDITS FE-III AND CU-II COMPLEXES

Authors
GAVRILOV AB MOVCHAN TI POMOGAILO AD
Citation
Ab. Gavrilov et al., PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .37. REDOX PROPERTIES AND ELECTROCHEMICAL POLYMERIZATION OF METHACRYLOYLACETONE ANDITS FE-III AND CU-II COMPLEXES, Russian chemical bulletin, 43(2), 1994, pp. 232-239
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
2
Year of publication
1994
Pages
232 - 239
Database
ISI
SICI code
1066-5285(1994)43:2<232:PAROMM>2.0.ZU;2-6
Abstract
Electroreduction of methacryloylacetone and its Fe-III and Cu-II compl exes was studied by cyclic voltammetry and preparative electrolysis on a Hg electrode. The possibility of the electropolymerization of the c ompounds at highly negative potentials (-2.0 V, vs see) has been demon strated. The polymers obtained were characterized by elemental analysi s, electronic, IR-, and Mossbauer spectroscopy.