STANNYLFORMYLATION OF 1,6-DIENES ACCOMPANIED BY 5-MEMBERED RADICAL RING-CLOSURE

Authors
RYU I KURIHARA A MURAOKA H TSUNOI S KAMBE N SONODA N
Citation
I. Ryu et al., STANNYLFORMYLATION OF 1,6-DIENES ACCOMPANIED BY 5-MEMBERED RADICAL RING-CLOSURE, Journal of organic chemistry, 59(25), 1994, pp. 7570-7571
Citations number
42
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
25
Year of publication
1994
Pages
7570 - 7571
Database
ISI
SICI code
0022-3263(1994)59:25<7570:SO1AB5>2.0.ZU;2-P
Abstract
Treatment of 1,6-dienes with tin hydride and AIBN (catalytic) under CO pressure leads to five-membered carbocycles flanked by stannylmethyl and formylmethyl groups at the adjacent carbons by way of a stannyl ra dical addition-cyclization-carbonylation sequence.