PREPARATION AND CHEMISTRY OF STABLE AZIDOIODINANES - DO-3,3-BIS(TRIFLUOROMETHYL)-3-(1H)-1,2-BENZIODOXOL 1-AZIDO-1,2-BENZIODOXOL-3-(1H)-ONE

Authors
ZHDANKIN VV KUEHL CJ KRASUTSKY AP FORMANECK MS BOLZ JT
Citation
Vv. Zhdankin et al., PREPARATION AND CHEMISTRY OF STABLE AZIDOIODINANES - DO-3,3-BIS(TRIFLUOROMETHYL)-3-(1H)-1,2-BENZIODOXOL 1-AZIDO-1,2-BENZIODOXOL-3-(1H)-ONE, Tetrahedron letters, 35(52), 1994, pp. 9677-9680
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
52
Year of publication
1994
Pages
9677 - 9680
Database
ISI
SICI code
0040-4039(1994)35:52<9677:PACOSA>2.0.ZU;2-U
Abstract
Azidoiodinanes 2,4,6 can be prepared from benziodoxols 1,3 and trimeth ylsilyl azide in the form of stable, crystalline compounds. These comp ounds are potentially useful reagents for electrophilic azidonation of organic substrates. For example, reaction of azide 6 with cyclohexene affords 2-azidocyclohexanone 7 in moderate yield.