SYNTHESIS OF FLUOROPHOSPHORANES VIA THE MITSUNOBU REACTION

Authors
HARVEY PJ JENKINS ID
Citation
Pj. Harvey et Id. Jenkins, SYNTHESIS OF FLUOROPHOSPHORANES VIA THE MITSUNOBU REACTION, Tetrahedron letters, 35(52), 1994, pp. 9775-9778
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
52
Year of publication
1994
Pages
9775 - 9778
Database
ISI
SICI code
0040-4039(1994)35:52<9775:SOFVTM>2.0.ZU;2-#
Abstract
Treatment of triphenylphosphine with potassium hydrogen fluoride or hy drogen fluoride-pyridine and diisopropyl azodicarboxylate in acetonitr ile or tetrahydrofuran, at room temperature results in the clean forma tion of difluorotriphenylphosphorane. Analogous results were obtained with other phosphines such as tributylphosphine and tris(dimethylamino ) phosphine.