Zq. Yao et al., THE ELECTRICAL-PROPERTIES OF SUB-5-NM OXYNITRIDE DIELECTRICS PREPAREDIN A NITRIC-OXIDE AMBIENT USING RAPID THERMAL-PROCESSING, IEEE electron device letters, 15(12), 1994, pp. 516-518
Ultrathin (<5 mn) dielectric films have been grown on [100] silicon us
ing rapid thermal processing (RTP) in a nitric oxide (NO) ambient. Int
erface state density, charge trapping properties, and interface state
generation during Fowler-Nordheim electron injection have been investi
gated. The films grown in NO have excellent electrical properties. The
se properties are explained in terms of a much stronger and large numb
er of Si-N bonds in both the bulk of the dielectric films and at the S
i-SiO2 interface region. The leakage currents are at least three order
s of magnitude lower than other reported results for similar thickness
es. The dielectric films grown in NO ambient are viewed as promising t
echnology for ultrathin dielectrics.