W. Scherer, QUANTUM AVERAGING .1. POINCARE-VON ZEIPEL IS RAYLEIGH-SCHRODINGER, Journal of physics. A, mathematical and general, 27(24), 1994, pp. 8231-8246
An exact analogue of the method of averaging in classical mechanics is
constructed for self-adjoint operators. It is shown to be completely
equivalent to the usual Rayleigh-Schrodinger perturbation theory but g
ives the sums over intermediate states in closed-form expressions. The
anharmonic oscillator and the Henon-Heiles system are treated as exam
ples to illustrate the quantum averaging method.