RH-LOADED CEO2-ZRO2 SOLID-SOLUTIONS AS HIGHLY EFFICIENT OXYGEN EXCHANGERS - DEPENDENCE OF THE REDUCTION BEHAVIOR AND THE OXYGEN STORAGE CAPACITY ON THE STRUCTURAL-PROPERTIES

Temperature-programmed reduction in a H-2/Ar mixture of Rh-loaded CeO2 -ZrO2 solid solutions with a ZrO2 content varying between 10 and 90% m ol and of monoclinic, tetragonal, and cubic structures is reported. It is shown that incorporation of ZrO2 into a solid solution with CeO2 s trongly promotes bulk reduction of the Rh-loaded solid solutions in co mparison to a Rh/CeO2 sample. The promotion of the bulk reduction resu lts in high oxygen storage capacity (OSC) as measured by oxygen uptake . A structural dependence of both reduction and oxidation processes is observed which is attributed to a higher oxygen mobility in the cubic structure compared to the tetragonal and monoclinic ones. (C) 1995 Ac ademic Press, Inc.