A theoretical model based on the grand partition function has been dev
eloped to investigate the role of size effects on surface tension and
surface segregation of liquid binary alloys. The necessary relation, w
hich connects the surface composition with surface tension through ord
er potential, surface coordination and volume ratio, is obtained. This
has been applied to liquid Na-Cs alloys. Likewise bulk properties, su
rface segregation and surface tension of Na-Cs liquid alloys are also
affected appreciably by the size difference and are anomalous around C
(Na) = 0.8.