FORMULATION OF GENERALIZED EQUATIONS FOR REDOX TITRATION CURVES

The paper provides several examples of rigorous formulation of redox t itration curves. All available physico-chemical data of a system consi dered are employed, and no simplifying assumptions are made. A new, ge neralized notation of the electron balance and an iterative computer p rogram were applied for this purpose. The approach proposed enable: a) to construct titration curves and the plots of log[X(i)] vs. fraction titrated PHI for different species X(i), b) to formulate the reaction s proceeding at any stage of the titration together with their efficie ncies and c) to locate characteristic points on the titration curves.