SYNERGIC EXTRACTION EQUILIBRIUM AND SUBSTOICHIOMETRIC EXTRACTION OF IRON(II) WITH 2-THENOYLTRIFLUOROACETONE AND TRIOCTYLPHOSPHINE OXIDE

Authors
TSUKAHARA S ZAITSU K TANAKA N SUZUKI N
Citation
S. Tsukahara et al., SYNERGIC EXTRACTION EQUILIBRIUM AND SUBSTOICHIOMETRIC EXTRACTION OF IRON(II) WITH 2-THENOYLTRIFLUOROACETONE AND TRIOCTYLPHOSPHINE OXIDE, Radiochimica Acta, 65(4), 1994, pp. 245-248
Citations number
19
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
Journal title
Radiochimica Acta → ACNP
ISSN journal
00338230
Volume
65
Issue
4
Year of publication
1994
Pages
245 - 248
Database
ISI
SICI code
0033-8230(1994)65:4<245:SEEASE>2.0.ZU;2-Z
Abstract
The synergic extraction of iron(II) was carried out with 2-thenoyltrif luoroacetone (Htta) and trioctylphosphine oxide (topo) into heptane. T he extracted species was considered to be Fe(tta)2(topo) and Fe(tta)2( topo)2, and the synergic extraction constants were obtained. The subst oichiometric extraction of iron(II) was first attained in the above ex traction system within 30 min. Its reproducibility was high (RSD 1.0%) in the Fe2+ range of 18.7-192 mug.