EQUIVALENCE BETWEEN 2-DIMENSIONAL AND 3-DIMENSIONAL PHASES OF ALIPHATIC CHAIN DERIVATIVES

Authors
PETERSON IR KENN RM
Citation
Ir. Peterson et Rm. Kenn, EQUIVALENCE BETWEEN 2-DIMENSIONAL AND 3-DIMENSIONAL PHASES OF ALIPHATIC CHAIN DERIVATIVES, Langmuir, 10(12), 1994, pp. 4645-4650
Citations number
71
Categorie Soggetti
Chemistry Physical
Journal title
Langmuir → ACNP
ISSN journal
07437463
Volume
10
Issue
12
Year of publication
1994
Pages
4645 - 4650
Database
ISI
SICI code
0743-7463(1994)10:12<4645:EB2A3P>2.0.ZU;2-S
Abstract
We demonstrate a detailed structural equivalence between 7 of the 12 k nown condensed water-surface monolayer phases of long-chain fatty acid s and 7 of the 11 known bulk solid phases observed in long-chain alkra nes. Two second-order phase transitions are common to both. Thermodyna mic parameters are established in both systems for one of these and th ey are consistent with the proposed equivalence.