SYNTHESIS AND CHARACTERIZATION OF ORGANOMETALLIC THIO-SCHIFF BASES AND THEIR COPPER(II) CHELATES

Authors
ZHAO G LOU F MA YX
Citation
G. Zhao et al., SYNTHESIS AND CHARACTERIZATION OF ORGANOMETALLIC THIO-SCHIFF BASES AND THEIR COPPER(II) CHELATES, Transition metal chemistry, 19(6), 1994, pp. 567-570
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
19
Issue
6
Year of publication
1994
Pages
567 - 570
Database
ISI
SICI code
0340-4285(1994)19:6<567:SACOOT>2.0.ZU;2-T
Abstract
Four organometallic thio-Schiff base ligands derived from ferrocene of general formula C(5)H(5)FeC(5)H(4)CR = NNHCSSR' (R = H or Me, R' = Me or CH,Ph) (HL), and their copper(II) chelates [CuL(2)] and [Cu(HL)(2) ]Cl-2, were prepared and characterized by physicochemical and spectros copic methods. The thio-Schiff bases act as bidentate ligands and coor dinate to copper(II) in the enolic form in EtOH and in the keto form i n THF.