THE STRUCTURE AND MAGNETIC-PROPERTIES OF THE DI-MU-PYRAZOLATE COMPLEX[CU-2(PEAH(2))(NO3)(H2O)](NO3) [PEAH(3)=3,5-BIS(N-ETHYLAMIDO)PYRAZOLE]

Authors
FU DG WANG GX ZHOU ZY ZHOU XG
Citation
Dg. Fu et al., THE STRUCTURE AND MAGNETIC-PROPERTIES OF THE DI-MU-PYRAZOLATE COMPLEX[CU-2(PEAH(2))(NO3)(H2O)](NO3) [PEAH(3)=3,5-BIS(N-ETHYLAMIDO)PYRAZOLE], Transition metal chemistry, 19(6), 1994, pp. 592-594
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
19
Issue
6
Year of publication
1994
Pages
592 - 594
Database
ISI
SICI code
0340-4285(1994)19:6<592:TSAMOT>2.0.ZU;2-F
Abstract
A complex of the formula [Cu-2(PEAH(2))(2)(NO3)(H2O)]-(N O-3) [PEAH(3) = 3,5-bis(N-ethylamido)pyrazole] was synthesized and its crystal stru cture determined by XRD methods. It consists of a dimeric cation with two bridging pyrazolate groups and a NO; anion. The geometries of the coordination polyhedra around the copper(II) ions are distorted square pyramidal. The variable temperature (20-300 K) magnetic susceptibilit y data gave the antiferromagnetic interaction constant as J = - 19l cm (-1), showing that the pyrazole molecule is very effective in transmit ting the exchange interaction.