PREPARATION AND MOSSBAUER STUDY OF IRON-MERCURY COMPLEXES CONTAINING ISOCYANIDE AND CARBONYL LIGANDS

Authors
MORIGAKI MK MACHADO LC LARICA C DIAS GHM
Citation
Mk. Morigaki et al., PREPARATION AND MOSSBAUER STUDY OF IRON-MERCURY COMPLEXES CONTAINING ISOCYANIDE AND CARBONYL LIGANDS, Transition metal chemistry, 19(6), 1994, pp. 599-602
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
19
Issue
6
Year of publication
1994
Pages
599 - 602
Database
ISI
SICI code
0340-4285(1994)19:6<599:PAMSOI>2.0.ZU;2-W
Abstract
Complexes [Fe(t-BuNC)(n)(CO)(5-n)] (n = 1 or 2) react with equimolar a mounts of mercury(II) halides in acetone to form neutral iron-mercury adducts [Fe(t-BuNC)(CO)(4)(HgX(2))] and [Fe(t-BuNC)(2)(CO)(3)(HgX(2))] (X = Cl or I), while [Fe(t-BuNC)(5)] reacts with solid mercury halide s in petroleum ether to give the salts [Fe(t-BuNC)(5)(HgX)]HgX(3) (X = Br or I). Product assessment was based upon analytical and spectrosco pic data, the Mossbauer effect and on molar conductivity studies.