We have searched for 6.6-GHz methanol maser emission from the directio
ns of more than 200 OH masers, together with a number of other sites o
f star formation. We have also observed previously reported methanol m
asers south of declination 24-degrees. Where we detected methanol emis
sion, we measured its position and have found more than 40 instances o
f small clusters of sources. We present observations of a total of 245
methanol masers with peak intensities ranging from 0.3 to 5000 Jy. Fo
r a typical source, the velocity range of the emission is quite large
- commonly 10 km s-1 and, in a few instances, exceeding 20 km s-1. Som
e of the largest velocity ranges are suggestive of emission from an ou
tflow region as well as a central source. Our observations over severa
l epochs show that many sources possess at least some features whose i
ntensity varies on a time-scale of several months. Towards most of the
6.6-GHz masers we have searched for 12-GHz methanol maser emission, a
nd have made 131 detections; the median ratio of 12- to 6.6-GHz intens
ity is 0.11. We discuss the general properties of this large sample of
6.6-GHz methanol masers. They appear to be more prevalent than OH mas
ers, with intensities typically seven times higher, and are thus excel
lent tracers of compact H II regions and sites of recent star formatio
n.