A. Kaune et A. Kettrup, TREATMENT OF VALUES BELOW THE DETECTION LIMITS IN CORRELATION-ANALYSIS OF CHLORINATED DIOXINS AND RELATED-COMPOUNDS, Chemosphere, 29(9-11), 1994, pp. 1811-1818
Concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans
(PCDD/F) in incinerator exhaust gas were correlated with concentration
s of other aromatic compounds. Values below the limits of detection (L
OD) are treated as missing. However, by doing so misleading results co
ncerning whether or not a correlation exists may be produced. To addit
ionally verify the results, we propose the following procedure. Replac
e non detected concentrations by any value smaller than the minimum of
detected concentrations and compute Spearman's rank correlation coeff
icient. If this coefficient is not significant it is proposed to assum
e that no correlation exists.