Incineration of unsorted municipal solid waste (MSW) is known to gener
ate polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) whic
h can be removed from the flue gas to a level below 0.1 ng/m(3) I-TEQ.
Combustion of coal, which contains minor amounts of chlorine, in powe
r plants normally gives rise to PCDD/F emissions below 0.01 ng/m(3) I-
TEQ. According to theory the formation of PCDD/F is prohibited by the
presence of sulphur in excess of chlorine in the fuel. As solid fuels
are used in amounts approximately one to two orders of magnitude highe
r than MSW is generated, it is apparent that combustible waste fractio
ns could be used as co-fuel in power production. This has been demonst
rated for Mixed Plastics together with wood and coal. In the present i
nvestigation various combustible packaging scrap and waste fractions w
ere co-combusted in a CFB-boiler together with peat and coal. It was g
enerally concluded that emissions from co-combustion did not significa
ntly exceed those of the primary fuels and particularly that the emiss
ions of dioxins were well below 0.1 ng/Nm(3) I-TEQ even when the flue
gas treatment equipment in the boiler plant consisted of electrostatic
precipitators only.