PERICYCLIC KEY REACTIONS IN BIOLOGICAL-SYSTEMS AND BIOMIMETIC SYNTHESES
Citation
U. Pindur et Gh. Schneider, PERICYCLIC KEY REACTIONS IN BIOLOGICAL-SYSTEMS AND BIOMIMETIC SYNTHESES, Chemical Society reviews, 23(6), 1994, pp. 409-415
Categorie Soggetti
Chemistry
SICI code
0306-0012(1994)23:6<409:PKRIBA>2.0.ZU;2-8
Abstract
A variety of pericyclic key reactions in biological systems are explor
ed and lead stereospecifically to many natural products. Some examples
of pericyclic reactions taking place in biological systems are discus
sed and classified on the basis of reaction mechanism type. Some biomi
metic syntheses are also included that complete the biosynthetic steps
. There is evidence that some of the biological pericyclic reactions l
eading to enantiomerically pure compounds are catalysed by enzymes.