The method of cross-sectional scanning tunnelling microscopy (STM) is
described. Illustrative examples are given of studies of Ill-V semicon
ductor systems, including AlxGa(1-x)As/GaAs superlattices, InAs/GaSb s
uperlattices and low-temperature-grown GaAs. Physical properties studi
ed include alloy clustering, interface roughness, band offsets, quantu
m subbands and point defects. In each case, STM permits the observatio
n of structural features on an atomic scale. The associated electronic
spectroscopy for states a few eV on either side of the Fermi level ca
n be determined. Such information is relevant for the operation of dev
ices constructed from these layered semiconductor systems.