Ar. Byrne et M. Dermelj, COMPREHENSIVE RNAA OF CADMIUM, COBALT, NICKEL, AND COPPER USING CD-109, CO-57, AND REACTOR-PRODUCED CU-67 AS RADIOISOTOPIC YIELD MONITORS, Biological trace element research, 43-5, 1994, pp. 87-94
An existing radiochemical NAA procedure for Cd, Co, and Cu was improve
d to allow determination of individual radiochemical yields by the rad
ioisotopic tracer technique, thus eliminating errors owing to variable
recovery. Cd-109 was used as tracer for Cd determination via Cd-115/I
n-115m, Co-57 for Co via Co-60, and potentially for Ni via Co-58, wher
eas as a novelty Cu-67, produced by reactor irradiation of ZnO of natu
ral isotopic composition (by the Zn-67 [n,p] Cu-67 reaction) was used
for Cu via the indicator nuclide Cu-64. The simple production and puri
fication of Cu-67 by anion exchange is described. Results for biologic
al RMs are given and discussed.