Y. Yamada et al., EFFECT OF DEBONDING AT THE PHASE INTERFACE ON YOUNGS MODULUS OF SINTERED PSZ STAINLESS STEEL COMPOSITE/, Materials transactions, JIM, 35(11), 1994, pp. 814-820
A theoretical estimation has been made on the effect of debonding at t
he phase interface on Young's modulus in sintered PSZ/stainless steel
composites with an abnormal deterioration of Young's modulus. The pres
ent analysis is based on Eshelby's equivalent inclusion method and a d
ebonding model. A comparison is made between the theoretically predict
ed Young's modulus and experimental data for the composites having thr
ee different combinations of original powder size. The theoretical cal
culation shows that the Young's modulus decreases with increasing frac
tion of debonding. The fraction of debonding can be, in turn, predicte
d by comparing the theoretical calculation with the experimental data
which have been found to depend on the composition of PSZ and original
particle size. The particle size dependence on debonding has been dis
cussed using the Weibull distribution, which shows that the coarser di
spersoids have more debonded interface. The composition dependence has
been explained by the variation of interface's residual stress with c
omposition, which is generated by the mismatch of thermal expansion co
efficients between the matrix and the dispersed particles, and the res
idual stress is compressive at the metal-rich side and tensile at the
ceramic-rich side. The tensile stress at the interface enhances the de
bonding, however, the compressive stress defend it and improve the You
ng's modulus. The dependence of the abnormal deterioration of Young's
modulus on the composition and particle size has been well accounted f
or.