ENANTIOSELECTIVE PERMEATION OF RACEMATES THROUGH A SOLID (-POLY(2-[DIMETHYL(10-PINANYL)SILYL]NORBORNADIENE) MEMBRANE())

Authors
AOKI T OHSHIMA M SHINOHARA KI KANEKO T OIKAWA E
Citation
T. Aoki et al., ENANTIOSELECTIVE PERMEATION OF RACEMATES THROUGH A SOLID (-POLY(2-[DIMETHYL(10-PINANYL)SILYL]NORBORNADIENE) MEMBRANE()), Polymer, 38(1), 1997, pp. 235-238
Citations number
11
Categorie Soggetti
Polymer Sciences
Journal title
Polymer → ACNP
ISSN journal
00323861
Volume
38
Issue
1
Year of publication
1997
Pages
235 - 238
Database
ISI
SICI code
0032-3861(1997)38:1<235:EPORTA>2.0.ZU;2-8
Abstract
A novel norbornadiene polymer having optically active pinanyl groups i n the pendant groups was synthesized as an optical resolution membrane material. The resulting polymer membrane showed highly enantioselecti ve permeability for racemic propranolol used as a medicine. The permea bility of tryptophan was much higher than that of a (+)-poly{1-[dimeth yl(10-pinanyl)silyl]-1-propyne} membrane we reported previously. Copyr ight (C) 1996 Elsevier Science Ltd.