REACTION ACTIVITY AND SELECTIVITY AS A FUNCTION OF SOLUTION IONIC-STRENGTH IN OCT-1-ENE HYDROFORMYLATION WITH SULFONATED PHOSPHINES

Authors
DING H HANSON BE
Citation
H. Ding et Be. Hanson, REACTION ACTIVITY AND SELECTIVITY AS A FUNCTION OF SOLUTION IONIC-STRENGTH IN OCT-1-ENE HYDROFORMYLATION WITH SULFONATED PHOSPHINES, Journal of the Chemical Society, Chemical Communications, (24), 1994, pp. 2747-2748
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
24
Year of publication
1994
Pages
2747 - 2748
Database
ISI
SICI code
0022-4936(1994):24<2747:RAASAA>2.0.ZU;2-T
Abstract
Salt concentration has a considerable influence on the activity and se lectivity of water-soluble hydroformylation catalysts derived from Rh( acac)(CO)(2) and the sulfonated phosphine, P[C6H4(CH2)(3)C6H4SO3Na](3) ; addition of Na2SO4 or Na2HPO4 to the catalysts enhances the both the rate and selectivity of the hydroformylation reaction.