TANDEM TRANSFORMATIONS INITIATED BY THE MIGRATION OF A SILYL GROUP - SOME NEW SYNTHETIC APPLICATIONS OF SILYLOXIRANES

Authors
JANKOWSKI P RAUBO P WICHA J
Citation
P. Jankowski et al., TANDEM TRANSFORMATIONS INITIATED BY THE MIGRATION OF A SILYL GROUP - SOME NEW SYNTHETIC APPLICATIONS OF SILYLOXIRANES, Synlett, (12), 1994, pp. 985-992
Citations number
66
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
12
Year of publication
1994
Pages
985 - 992
Database
ISI
SICI code
0936-5214(1994):12<985:TTIBTM>2.0.ZU;2-2
Abstract
The trimethylsilyl group and other silicon-containing groups are able to migrate to anionic centers within the molecule. This phenomenon is used to generate tandem processes involving a silyl group migration - a leaving group elimination in systems equipped with a silyl-, oxido-, and leaving group. Applications of silyloxiranes to synthesis invokin g tandem processes are described. Other synthetic applications of sily loxiranes based upon the cooperative reactions of silyl-, oxide (hydro xy) and leaving group are discussed.