SIMULTANEOUS BINDING OF SOFT AND HARD METALS TO A PYRIMIDINE NUCLEOBASE - PREPARATION AND X-RAY STRUCTURE OF [(EN)PD(1-MET)(2)NA-2](NO3)(2)CENTER-DOT-H2O (1-MET=1-METHYLTHYMINE ANION)

Authors
MICKLITZ W LIPPERT B LIANZA F ALBINATI A
Citation
W. Micklitz et al., SIMULTANEOUS BINDING OF SOFT AND HARD METALS TO A PYRIMIDINE NUCLEOBASE - PREPARATION AND X-RAY STRUCTURE OF [(EN)PD(1-MET)(2)NA-2](NO3)(2)CENTER-DOT-H2O (1-MET=1-METHYLTHYMINE ANION), Inorganica Chimica Acta, 227(1), 1994, pp. 5-10
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
227
Issue
1
Year of publication
1994
Pages
5 - 10
Database
ISI
SICI code
0020-1693(1994)227:1<5:SBOSAH>2.0.ZU;2-Q
Abstract
The crystal structure of [(en)Pd(1-MeT)(2)Na-2](NO3)(2).H2O, where 1-M eT = 1-methylthymine anion, C6H7N2O2, is reported. The compound crysta llizes in the monoclinic system, space group P2(1)/c with a=8.203(1), b=20.908(5), c=13.644(5) Angstrom, beta=98.35(2)degrees, V=2316(2) Ang strom(3). Pd binding is through N3 of the two 1-MeT rings. The two Na are coordinated to two O4 and two O2 oxygens of the 1-MeT rings, resp ectively. The compound represents the first structurally characterized example of M,M'(2) stoichiometry derived from a cis-a(2)ML(2) compoun d.