SYNTHESES OF RUTHENIUM IRIDIUM HETEROBIMETALLIC COMPLEXES USING TRIDENTATE PHOSPHINE-LIGANDS

Authors
NAWAR N SMITH AK
Citation
N. Nawar et Ak. Smith, SYNTHESES OF RUTHENIUM IRIDIUM HETEROBIMETALLIC COMPLEXES USING TRIDENTATE PHOSPHINE-LIGANDS, Inorganica Chimica Acta, 227(1), 1994, pp. 79-83
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
227
Issue
1
Year of publication
1994
Pages
79 - 83
Database
ISI
SICI code
0020-1693(1994)227:1<79:SORIHC>2.0.ZU;2-8
Abstract
Complexes of the type [Ru(C5H5)Cl{(PPh(2))(2)C=CH2}] undergo Michael-t ype addition with a diphenylphosphine and the products can be used for further syntheses of heterobimetallic complexes. The uncoordinated ph osphine group of [Ru(C5H5)Cl{(PPh(2))(2)CHCH(2)PPh(2)}] (1) reacts wit h Ir-4(CO)(12) to give mono-, di- and tri-substituted heterobimetallic cluster complexes 2, 3 and 4, respectively.