ISOMERIZATION OF ALLYL ALCOHOLS WITH RHODIUM(I) COMPLEXES

Authors
TRZECIAK AM ZIOLKOWSKI JJ
Citation
Am. Trzeciak et Jj. Ziolkowski, ISOMERIZATION OF ALLYL ALCOHOLS WITH RHODIUM(I) COMPLEXES, Gazzetta chimica italiana, 124(10), 1994, pp. 403-409
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
124
Issue
10
Year of publication
1994
Pages
403 - 409
Database
ISI
SICI code
0016-5603(1994)124:10<403:IOAAWR>2.0.ZU;2-Y
Abstract
The results of the isomerization reaction of some allyl alcohols (2-pr open-l-ol, 3-buten-2-ol and 1-octen-3-ol) with the Rh(I) complexes HRh (CO)(PPh3)3, HRh{P(OPh)3}4, Rh{P(OPh)3}4ClO4 are presented. The mechan ism of the Rh{P(OPh)3}3{P(OPh)2(OC6H4)}-catalyzed isomerization is dis cussed.