This paper is a brief survey on the preparation of latexes bearing cov
alently bonded functional groups using various routes. Recent methods
are presented using water soluble functional (or surface active) initi
ators, monomers or macromonomers. For tailor synthesis, the copolymeri
sation approach of a basic monomer with a functional monomer under emu
lsifier-free conditions is generally the more suitable and versatile o
ne. More progress should be pursued in this field in order to design b
etter adapted chemical structures which will improve their use in radi
cal-initiated heterogeneous conditions and favour surface incorporatio
n.