Vg. Geethamma et al., SHORT COIR FIBER-REINFORCED NATURAL-RUBBER COMPOSITES - EFFECTS OF FIBER LENGTH, ORIENTATION, AND ALKALI TREATMENT, Journal of applied polymer science, 55(4), 1995, pp. 583-594
Natural rubber is reinforced with untreated coir fiber chopped to diff
erent lengths, viz., 6, 10, and 14 mm. Mixes were also prepared using
10 mm-long coir fibers treated with 5% sodium hydroxide solution for d
ifferent time intervals, viz., 4, 24, 48, and 72 h. These composites w
ere vulcanized at 150 degrees C. The vulcanization parameters, process
ability characteristics, and stress-strain properties of these composi
tes were analyzed. The rubber-coir interface bonding was improved by t
he addition of a resorcinol-hexamethylenetetramine dry-bonding system.
The reinforcing property of the alkali-treated fiber was compared wit
h that of the untreated one. The extent of fiber orientation in the co
mposite was determined from green strength measurements. From anisotro
pic swelling studies, the extent of fiber alignment and the strength o
f fiber-rubber interface adhesion were analyzed. Scanning electron mic
roscopic studies were carried out to investigate the fiber surface mor
phology, fiber pullout, and fiber-rubber interface. (C) 1995 John Wile
y and Sons, Inc.