X-ray photoelectron spectroscopy (XPS) measurements of core-level and
valence band have been used to study the practical Pd/Si interface. Ev
idence of silicide, Pd2Si, formed by chemical reaction at this interfa
ce has been obtained. A monotonic increase of the branching ratio for
two Pd 3d spin-orbit split peaks of silicide, Pd2Si, with decreasing p
hotoemission angles was measured. Some possible interpretations for th
is change are also presented.