EXTRACTION AND DETERMINATION OF MICROGRAM AMOUNTS OF MOLYBDENUM(VI) AND TUNGSTEN(VI) IN CARBON-STEEL, MILD-STEEL, PLAIN STEEL AND MN-MO STEEL

Authors
BARVE AD SHINDE VM
Citation
Ad. Barve et Vm. Shinde, EXTRACTION AND DETERMINATION OF MICROGRAM AMOUNTS OF MOLYBDENUM(VI) AND TUNGSTEN(VI) IN CARBON-STEEL, MILD-STEEL, PLAIN STEEL AND MN-MO STEEL, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 33(12), 1994, pp. 1126-1128
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
33
Issue
12
Year of publication
1994
Pages
1126 - 1128
Database
ISI
SICI code
0376-4710(1994)33:12<1126:EADOMA>2.0.ZU;2-1
Abstract
A method is proposed for the extraction of microgram amounts of molybd enum(VI) and tungsten(VI) from halide medium using tris(2-ethylhexyl) phosphate dissolved in toluene as an extractant. Various experimental parameters involved in the use of the method such as acid concentratio n, period of equilibration, nature of stripping agents and interferenc e by diverse ions have been studied. The logD-logC plot is used to asc ertain probable extractable species. The method has been applied for s eparation of molybdenum(VI) and tungsten(VI) in alloys like carbon ste el, mild steel, plain steel and Mn-Mo steel. The analysis requires 15- 20 min.