Agricultural and industrial solid wastes can be recycled as nonconvent
ional adsorbents if they are inert and harmless to reduce the cost of
the wastewater treatments. Waste Fe(III)/Cr(III) hydroxide, generated
in the treatment of Cr(VI) bearing wastewaters in a fertilizer industr
y, was used for the adsorption of Congo red (direct dye) from aqueous
solution. The parameters studied include agitation time, initial dye c
oncentration, pH and adsorbent dosage. The adsorption capacity was eva
luated by using both the Langmuir and Freundlich adsorption isotherm m
odels. Removal of the dye was maximum, 91% at pH 3. Low desorption (9%
) with water seems to indicate that the dye is mostly held by the adso
rbent through ion-exchange.