BORON-CONTAINING AND PHOSPORUS-CONTAINING HETEROCYCLES - FIRST EVIDENCE OF A TRANSIENT CYCLIC PHOSPHABOROLANE WITH P-H AND B-H BONDS

Authors
GAUMONT AC BOURUMEAU K DENIS JM GUENOT P
Citation
Ac. Gaumont et al., BORON-CONTAINING AND PHOSPORUS-CONTAINING HETEROCYCLES - FIRST EVIDENCE OF A TRANSIENT CYCLIC PHOSPHABOROLANE WITH P-H AND B-H BONDS, Journal of organometallic chemistry, 484(1-2), 1994, pp. 9-12
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
484
Issue
1-2
Year of publication
1994
Pages
9 - 12
Database
ISI
SICI code
0022-328X(1994)484:1-2<9:BAPH-F>2.0.ZU;2-V
Abstract
A stable cyclic phosphine-borane was prepared by an intramolecular reg ioselective hydroboration of the allylphosphine-borane precursor. Unde r flash vacuum thermolysis (FVT) conditions, the corresponding transie nt phosphaborolane was formed and was characterized by high-resolution mass spectrometry using a tandem FVT/MS device.