THE GENERATION OF 1,1-DIMETHYLSILANIMINE BY FLASH VACUUM THERMOLYSIS

Authors
LETULLE M SYSTERMANS A RIPOLL JL GUENOT P
Citation
M. Letulle et al., THE GENERATION OF 1,1-DIMETHYLSILANIMINE BY FLASH VACUUM THERMOLYSIS, Journal of organometallic chemistry, 484(1-2), 1994, pp. 89-91
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
484
Issue
1-2
Year of publication
1994
Pages
89 - 91
Database
ISI
SICI code
0022-328X(1994)484:1-2<89:TGO1BF>2.0.ZU;2-#
Abstract
1,1-dimethylsilanimine (Me(2)Si=NH) was generated from two different p recursors, under flash vacuum thermolysis (FVT) conditions, either by retro-[2 + 2] or by retro-ene cleavage. This very reactive silanimine was characterized by formation of its cyclo-dimer, analyzed by FVT/HRM S, as well as by the production of its adduct with t-butanol. The gene ration in these thermolyses of N-t-butyl-1,1-dimethylsilanimine and N- dimethylsilyl-1,1-dimethylsilanimine was also demonstrated.