REACTION OF URANIUM TETRACHLORIDE WITH TRIMETHYLSILYLCYCLOPENTADIENE - CRYSTAL-STRUCTURE OF A DICHLOROMETHANE ADDUCT OF MU-CL))(3)(MU(3)-CL)(2)][(U(CP)CL-2)(2)(MU-CL)(3)] (CP=ETA-C5H5)

Authors
ARLIGUIE T EPHRITIKHINE M LANCE M VIGNER J NIERLICH M
Citation
T. Arliguie et al., REACTION OF URANIUM TETRACHLORIDE WITH TRIMETHYLSILYLCYCLOPENTADIENE - CRYSTAL-STRUCTURE OF A DICHLOROMETHANE ADDUCT OF MU-CL))(3)(MU(3)-CL)(2)][(U(CP)CL-2)(2)(MU-CL)(3)] (CP=ETA-C5H5), Journal of organometallic chemistry, 484(1-2), 1994, pp. 195-201
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
484
Issue
1-2
Year of publication
1994
Pages
195 - 201
Database
ISI
SICI code
0022-328X(1994)484:1-2<195:ROUTWT>2.0.ZU;2-I
Abstract
The uranium tetrachloride reacts in dichloromethane with 1 and 3 equiv alents of trimethylsilylcyclopentadiene to give [U(cp)Cl-3] (1) and [U (cp)(3)Cl] (3) respectively (cp = eta-C5H5). The title compound 2 was isolated from the reaction of UCl4 with 2 equivalents of the silylated cyclopentadiene. Complex 2 is in equilibrium with 1 and 3 in refluxin g dichloromethane.