MULTIPLE CYCLOPENTADIENYL SUBSTITUTION OF DISILANES AND TRISILANES

Citation
K. Schenzel et K. Hassler, MULTIPLE CYCLOPENTADIENYL SUBSTITUTION OF DISILANES AND TRISILANES, Journal of organometallic chemistry, 484(1-2), 1994, pp. 1-4
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
484
Issue
1-2
Year of publication
1994
Pages
1 - 4
Database
ISI
SICI code
0022-328X(1994)484:1-2<1:MCSODA>2.0.ZU;2-#
Abstract
The cyclopentadienyl substituted di- and trisilanes (Cp(2)SiMe)(2), (C pSiMe(2))(2) and Cp(2)Si(SiMe(3))(2), (Cp = C5H5) were prepared and ch aracterized by Si-29-NMR and vibrational (IR) spectroscopy as well as elemental analyses. All silanes exist as mixtures of isomers resulting from silatropic rearrangements.