The site occupancy of Si introduced as a dopant in the growth of GaAs
on GaAs(111)A has been shown to be very sensitive to growth conditions
. We have examined the effect of modulating the AS4 and Ga fluxes on t
his behaviour. Supplying Ga and As sequentially rather than simultaneo
usly always results in a much stronger tendency for the Si to occupy a
n As site and act as an acceptor than for material grown by convention
al molecular beam epitaxy. The same result is obtained irrespective of
whether the Si is supplied with the As or Ga.