TEMPERATURE-DEPENDENCE OF THE ROTATIONAL RELAXATION-TIME IN NITROGEN

Citation
Ae. Belikov et al., TEMPERATURE-DEPENDENCE OF THE ROTATIONAL RELAXATION-TIME IN NITROGEN, Chemical physics letters, 231(4-6), 1994, pp. 444-448
Citations number
13
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
231
Issue
4-6
Year of publication
1994
Pages
444 - 448
Database
ISI
SICI code
0009-2614(1994)231:4-6<444:TOTRRI>2.0.ZU;2-L
Abstract
An electron-beam fluorescence method has been used to study the temper ature dependence of the rotational relaxation time characterizing the R-T energy transfer resulting from the free jet expansion of nitrogen for temperatures in the range 6-320 K. Theoretical values calculated i n a semiclassical approximation are in good agreement with the present experimental data. The parameters of the anisotropic part of both the repulsive and attractive parts of the interaction potential have been determined earlier through a fitting procedure using the results of o ther experiments.