SYNTHESIS, CHARACTERIZATION AND THE CRYSTAL-STRUCTURE OF A CIS-DIOXOVANADIUM(V) COMPLEX OF A TRIDENTATE SCHIFF-BASE LIGAND

Authors
LIU HX WANG W WANG X TAN MY
Citation
Hx. Liu et al., SYNTHESIS, CHARACTERIZATION AND THE CRYSTAL-STRUCTURE OF A CIS-DIOXOVANADIUM(V) COMPLEX OF A TRIDENTATE SCHIFF-BASE LIGAND, Journal of coordination chemistry, 33(4), 1994, pp. 347-352
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
33
Issue
4
Year of publication
1994
Pages
347 - 352
Database
ISI
SICI code
0095-8972(1994)33:4<347:SCATCO>2.0.ZU;2-N
Abstract
The title complex, [VO2{C6H5C(O)CHC(CH3)NNC(O)CH2(NC5H5)}].C2H5OH, was synthesized and characterized by elemental analysis and spectroscopy. Yellow crystals of the complex are monoclinic, space group P2(1)/a wi th a = 10.690(2), b = 16.008(3), c = 13.164(4)Angstrom, beta = 107.03( 2)degrees, V = 2153.9(18)Angstrom(3), F(000) = 880 and Dc = 1.305 g cm (-3) for Z = 4. X-ray structure analysis shows that the vanadium coord ination number is five and the coordination polyhedron is a distorted trigonal bipyramid.