SOLVENT EFFECTS IN THE FLUORINATION OF AROMATIC-MOLECULES WITH F-TEDA-BF4

Authors
ZUPAN M ISKRA J STAVBER S
Citation
M. Zupan et al., SOLVENT EFFECTS IN THE FLUORINATION OF AROMATIC-MOLECULES WITH F-TEDA-BF4, Journal of fluorine chemistry, 70(1), 1995, pp. 7-8
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
70
Issue
1
Year of publication
1995
Pages
7 - 8
Database
ISI
SICI code
0022-1139(1995)70:1<7:SEITFO>2.0.ZU;2-P
Abstract
The type of functionalization of an aromatic molecule achieved with lo romethyl-4-fluoro-1,4-diazobicyclo-(2,2,2)octane bis-tetrafluoroborate , 'F-TEDA-BF4', in trifluoroacetic acid depends on its structure: naph thalene and phenanthrene gave fluorinated products, anthracene gave th e trifluoroacetate, while an addition process occurred with 9-methoxy- phenanthrene in methanol, and an addition-elimination process in trifl uoroacetic acid.