ESR STUDIES OF RADICAL BREAKDOWN FOR DI-T-BUTYL TRIOXIDE

Authors
KHURSAN SL SHERESHOVETS VV SHISHLOV NM KHALIZOV AF KOMISSAROV VD
Citation
Sl. Khursan et al., ESR STUDIES OF RADICAL BREAKDOWN FOR DI-T-BUTYL TRIOXIDE, Reaction kinetics and catalysis letters, 52(2), 1994, pp. 249-254
Citations number
7
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
52
Issue
2
Year of publication
1994
Pages
249 - 254
Database
ISI
SICI code
0133-1736(1994)52:2<249:ESORBF>2.0.ZU;2-8
Abstract
ESR data show thermal breakdown of the title trioxide into peroxy and alkoxy radicals ROO(.) and RO(.), respectively. Equilibrium constants were calculated for the formation of tetroxide ROOOOR from two peroxy radicals. Their thermodynamic parameters were determined at temperatur es ranging within 193-173 K.