SILYLATION EFFECT ON THE CATALYTIC PROPERTIES OF FEZSM-11 IN BENZENE OXIDATION TO PHENOL

Authors
PIRYUTKO LV PARENAGO OO LUNINA EV KHARITONOV AS OKKEL LG PANOV GI
Citation
Lv. Piryutko et al., SILYLATION EFFECT ON THE CATALYTIC PROPERTIES OF FEZSM-11 IN BENZENE OXIDATION TO PHENOL, Reaction kinetics and catalysis letters, 52(2), 1994, pp. 275-283
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
52
Issue
2
Year of publication
1994
Pages
275 - 283
Database
ISI
SICI code
0133-1736(1994)52:2<275:SEOTCP>2.0.ZU;2-V
Abstract
The outer surface of FeZSM-11 zeolite was selectively silylated withou t affecting the inner system of its channels. SiO2 deposition suppress ed both the acidity and catalytic activity of the outer surface in mes itylene isomerization. Neither zeolite activity, nor its stability in N2O benzene oxidation to phenol have changed upon silylation, This fac t gives evidence that the latter reaction proceeds primarily within th e zeolite channels.