ON APPLICATION OF THE GIBBS-DUHEM EQUATIO N FOR CALCULATING FREE-ENERGY OF MIXING OF POLYMER-SOLUTIONS

Citation
Ae. Chalykh et al., ON APPLICATION OF THE GIBBS-DUHEM EQUATIO N FOR CALCULATING FREE-ENERGY OF MIXING OF POLYMER-SOLUTIONS, Vysokomolekularnye soedinenia. Seria A, 36(12), 1994, pp. 2077-2080
Citations number
12
Categorie Soggetti
Polymer Sciences
ISSN journal
05075475
Volume
36
Issue
12
Year of publication
1994
Pages
2077 - 2080
Database
ISI
SICI code
0507-5475(1994)36:12<2077:OAOTGE>2.0.ZU;2-O
Abstract
Various methods for calculating free energy of mixing through the Gibb s-Duhem equation were compared. A new method for treating experimental data on concentration dependences of chemical potential was advanced. As compared with other known calculating procedures, this method was shown to provide more precise estimates of free energy of mixing.