CATALYTIC CARBONYLATION OF ETHYLENE IN THE PRESENCE OF THE PD(ACAC)(2)-M-PH(2)PC6H4SO3NA(H)-ACOH SYSTEM

Catalytic systems based on phosphine complexes of palladium have been developed for synthesizing propionic acid (monocarbonylation) and alte rnating (1:1) ethylene-carbon monoxide copolymers, i.e., polyketones ( polycarbonylation). m-(Diphenylphosphino)benzenesulfonic acid or its s odium salt were used as ligands. Monocarbonylation proceeds at atmosph eric pressure in dioxane or acetic acid solvents. Under high pressure, the reaction pathway can change from monocarbonylation, which occurs in the presence of the sodium salt of the ligand, to polycarbonylation when the sodium ion at the sulfo group is completely replaced by a pr oton. This change in reaction selectivity is observed when the process is performed in acetic acid. When the ligand is present both in the a cid and the neutral form, products of di- and oligocarbonylation are f ormed along with propionic acid and the polyketone. These products wer e characterized by H-1 and C-13 NMR spectra as alternating keto acids C2H5(COCH2CH2)(n)COOH, where n = 1 divided by 3. Kinetic equations wer e derived for the selective synthesis of propionic acid and polyketone s.