3-PHENOXY-1-PROPYNYL AND 3-PHENYLTHIO-1-PROPYNYL SUBSTITUTED DERIVATIVES OF SILICON AND GERMANIUM

Authors
LYASHENKO GS MEDVEDEVA AS BANNIKOVA OB VORONKOV MG
Citation
Gs. Lyashenko et al., 3-PHENOXY-1-PROPYNYL AND 3-PHENYLTHIO-1-PROPYNYL SUBSTITUTED DERIVATIVES OF SILICON AND GERMANIUM, Russian chemical bulletin, 43(3), 1994, pp. 471-473
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
3
Year of publication
1994
Pages
471 - 473
Database
ISI
SICI code
1066-5285(1994)43:3<471:3A3SD>2.0.ZU;2-3
Abstract
Reactions of bromomagnesiopropargyl phenyl ethers and their isostructu ral sulfides BrMgC=CCH(2)XPh (X = O, S) with MeVinSiCl(2), Me(CH2Cl)Si Cl2, EtSiHCl(2), and Me(2)SiHCl afforded the corresponding 3-phenoxy- and 3-phenylthio-1-propynyl substituted derivatives of silicon (PhXCH( 2)C=C)(2)SiRR(1) and PhXCH(2)C=CSiHMe(2) (X = O, S). Reactions of the above-mentioned Iotsitch reagents with GeCl4 led to the corresponding germanium derivatives (PhXCH(2)C=C)(4)Ge (X = O, S).