COMPLEXATION AND HYDROGENATION OF METHIONINE-CONTAINING N-ACETYLE-DEHYDRODIPEPTIDES

Authors
LISICHKINA IN VINOGRADOVA AI KURKOVSKAYA LN BACHURINA IB BELIKOV VM
Citation
In. Lisichkina et al., COMPLEXATION AND HYDROGENATION OF METHIONINE-CONTAINING N-ACETYLE-DEHYDRODIPEPTIDES, Russian chemical bulletin, 43(3), 1994, pp. 505-506
Citations number
3
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
3
Year of publication
1994
Pages
505 - 506
Database
ISI
SICI code
1066-5285(1994)43:3<505:CAHOMN>2.0.ZU;2-S
Abstract
The hydrogenation of the Fe-II complex of N-Ac-Delta Phe-(S)- or -(R)- Met over a Pd/C catalyst affords mainly N-Ac-(R)-Phe-(S)-Met or N-Ac-( S)-Phe-(R)-Met, correspondingly. In the reaction of mixed dipeptide co mplexes with Ca-II and Fe-II the predominance of one of the diastereom ers increases from 26 % (for complexes with Fe ions) to 38 %.