The geochemical peculiarities of carbonatites and the regularities of
ore concentration in alkaline-carbonatite complexes are considered at
the base of new petrogenetic model. According to the model the carbona
tites are considered as final products of mantle/crustal fluid-magmati
c systems. Along with mantle magmatic differentiation the carbonatitic
components are accumulated in metamagmatic processes i.e. carbonatisa
tion and alkali advent as a result of carbon dioxide flux from mantle/
crust and meteoric sources. General classification of carbonatite-alka
line rock series is presented based on alkaline-carbonatite complexes
of Europe, America, Africa and India. The concentration factors of rar
e metals (Nb, TR etc) are considered in concern with open or closed ty
pe of a system, abyssal level and metasomatic process scale.